Modelling galaxy spectra in presence of interstellar dust – II. From the ultraviolet to the far-infrared     

Lorenzo Piovan  Rosaria Tantalo  Cesare Chiosi 《Monthly notices of the Royal Astronomical Society》2006,370(3):1454-1478

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Speciation and solubility of heavy metals in contaminated soil using X-ray microfluorescence, EXAFS spectroscopy, chemical extraction, and thermodynamic modeling   总被引：3，自引：0，他引：3  

Tatiana A. Kirpichtchikova  Alain Manceau  Lorenzo Spadini  Matthew A. Marcus 《Geochimica et cosmochimica acta》2006,70(9):2163-2190

Synchrotron-based X-ray radiation microfluorescence (μ-SXRF) and micro-focused and powder extended X-ray absorption fine structure (EXAFS) spectroscopy measurements, combined with desorption experiments and thermodynamic calculations, were used to evaluate the solubility of metal contaminants (Zn, Cu, Pb) and determine the nature and fractional amount of Zn species in a near-neutral pH (6.5-7.0) truck-farming soil contaminated by sewage irrigation for one hundred years. Zn is the most abundant metal contaminant in the soil (1103 mg/kg), followed by Pb (535 mg/kg) and Cu (290 mg/kg). The extractability of Zn, Pb, and Cu with citrate, S,S-ethylenediaminedisuccinic acid (EDDS), and ethylenediaminetetraacetic acid (EDTA) was measured as a function of time (24 h, 72 h, 144 h), and also as a function of the number of applications of the chelant (5 applications each with 24 h of contact time). Fifty-three percent of the Zn was extracted after 144 h with citrate, 51% with EDDS and 46% with EDTA, compared to 69, 87, and 61% for Cu, and 24, 40, and 34% for Pb. Renewing the extracting solution removed more of the metals. Seventy-nine, 65, and 57% of the Zn was removed after five cycles with citrate, EDDS and EDTA, respectively, compared to 88, 100, and 72% for Cu, and 91, 65, and 47% for Pb. Application to the untreated soil of μ-SXRF, laterally resolved μ-EXAFS combined with principal component analysis, and bulk averaging powder EXAFS with linear least-squares combination fit of the data, identified five Zn species: Zn-sorbed ferrihydrite, Zn phosphate, Zn-containing trioctahedral phyllosilicate (modeled by the Zn kerolite, Si₄(Mg_1.65Zn_1.35)O₁₀(OH)₂ · nH₂O), willemite (Zn₂SiO₄), and gahnite (ZnAl₂O₄), in proportions of ∼30, 28, 24, 11, and less than 10%, respectively (precision: 10% of total Zn). In contrast to Cu and Pb, the same fractional amount of Zn was extracted after 24 h contact time with the three chelants (40-43% of the initial content), suggesting that one of the three predominant Zn species was highly soluble under the extraction conditions. Comparison of EXAFS data before and after chemical treatment revealed that the Zn phosphate component was entirely and selectively dissolved in the first 24 h of contact time. Preferential dissolution of the Zn phosphate component is supported by thermodynamic calculations. Despite the long-term contamination of this soil, about 79% of Zn, 91% of Pb, and 100% of Cu can be solubilized in the laboratory on a time scale of a few days by chemical complexants. According to metal speciation results and thermodynamic calculations, the lower extraction level measured for Zn is due to the Zn phyllosilicate component, which is less soluble than Zn phosphate and Zn ferrihydrite.  相似文献   

Dynamical constraints on some orbital and physical properties of the WD0137-349A/B binary system     

Lorenzo Iorio 《Astrophysics and Space Science》2007,312(3-4):337-341

In this paper I deal with the WD0137-349 binary system consisting of a white dwarf (WD) and a brown dwarf (BD) in a close circular orbit of about 116 min. I, first, constrain the admissible range of values for the inclination i by noting that, from looking for deviations from the third Kepler law, the quadrupole mass moment Q would assume unlikely large values, incompatible with zero at more than 1-sigma level for i≲35 deg and i≳43 deg. Then, by conservatively assuming that the most likely values for i are those that prevent such an anomalous behavior of Q, i.e. those for which the third Kepler law is an adequate modeling of the orbital period, I obtain i=39±2 deg. Such a result is incompatible with the value i=35 deg quoted in literature by more than 2 sigma. Conversely, it is shown that the white dwarf’s mass range obtained from spectroscopic measurements is compatible with my experimental range, but not for i=35 deg. As a consequence, my estimate of i yields an orbital separation of a=(0.59±0.05)R_⊙ and an equilibrium temperature of BD of T _eq=(2087±154) K which differ by 10% and 4%, respectively, from the corresponding values for i=35 deg.  相似文献   

Assessment of shallow landsliding by using a physically based model of hillslope stability     

Marco Borga  Giancarlo Dalla Fontana  Carlo Gregoretti  Lorenzo Marchi 《水文研究》2002,16(14):2833-2851

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RECENT DEVELOPMENTS IN DEBRIS FLOW RESEARCH IN ITALY     

刘希林 《中国地理科学(英文版)》1995,5(3):275-287

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Dendrogeomorphic dating of rockfalls on low‐latitude,high‐elevation slopes: Rodadero,Iztaccíhuatl volcano,Mexico     

Markus Stoffel  Michelle Bollschweiler  Lorenzo Vázquez‐Selem  Osvaldo Franco‐Ramos  David Palacios 《地球表面变化过程与地形》2011,36(9):1209-1217

Dynamics and rates of rockfalls have been repeatedly studied in mountain environments with archival records as well as lichenometric, radiocarbon or dendrogeomorphic approaches. In this study, we test the potential of conifers growing at a low‐latitude, high‐elevation site as a dendrogeomorphic tool to reconstruct to calendar dates associated rockfall activity. Analysis is based on tree‐ring records of Mexican mountain pine (Pinus hartwegii Lindl.) growing at timberline [~4000 m above sea level (a.s.l.)] and at the runout fringe of a north–northeast (NNE)‐facing slope of the dormant Iztaccíhuatl volcano (Mexico), which is subject to frequent rockfalls. The potential and limitations of tree‐ring data are demonstrated based on 67 rockfall impacts dated in the increment‐ring series of 24 trees since ad 1836. While findings of this paper are site‐specific, the study clearly shows the potential of dendrogeomorphic approaches in extra‐Alpine, low‐latitude environments and for the understanding of rockfall processes in space and time. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Global sensitivity analysis through polynomial chaos expansion of a basin-scale geochemical compaction model     

Luca Formaggia  Alberto Guadagnini  Ilaria Imperiali  Valentina Lever  Giovanni Porta  Monica Riva  Anna Scotti  Lorenzo Tamellini 《Computational Geosciences》2013,17(1):25-42

We present a model-driven uncertainty quantification methodology based on sparse grid sampling techniques in the context of a generalized polynomial chaos expansion (GPCE) approximation of a basin-scale geochemical evolution scenario. The approach is illustrated through a one-dimensional example involving the process of quartz cementation in sandstones and the resulting effects on the dynamics of the vertical distribution of porosity, pressure, and temperature. The proposed theoretical framework and computational tools allow performing an efficient and accurate global sensitivity analysis (GSA) of the system states (i.e., porosity, temperature, pressure, and fluxes) in the presence of uncertain key mechanical and geochemical model parameters as well as boundary conditions. GSA is grounded on the use of the variance-based Sobol indices. These allow discriminating the relative weights of uncertain quantities on the global model variance and can be computed through the GPCE of the model response. Evaluation of the GPCE of the model response is performed through the implementation of a sparse grid approximation technique in the space of the selected uncertain quantities. GPCE is then be employed as a surrogate model of the system states to quantify uncertainty propagation through the model in terms of the probability distribution (and its statistical moments) of target system states.  相似文献   

Dust emission in northern China: atmospheric emission–dispersion modelling of a major dust event     

Massimiliano Pasqui  Andrea Taramelli  Jonathan Barbour  Dalia Kirschbaum  Lorenzo Bottai  Caterina Busillo  Francesca Calastrini  Giovanni Gualtieri  Francesca Guarnieri  Chris Small 《地球表面变化过程与地形》2013,38(12):1354-1368

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Constraints on the location of a putative distant massive body in the Solar System from recent planetary data     

Lorenzo Iorio 《Celestial Mechanics and Dynamical Astronomy》2012,112(2):117-130

We analytically work out the long-term variations caused on the motion of a planet orbiting a star by a very distant, pointlike massive object X. Apart from the semi-major axis a, all the other Keplerian osculating orbital elements experience long-term variations which are complicated functions of the orbital configurations of both the planet itself and of X. We infer constraints on the minimum distance d _X at which X may exist by comparing our prediction of the long-term variation of the longitude of the perihelion \({\varpi}\) to the latest empirical determinations of the corrections \({\Delta\dot\varpi}\) to the standard Newtonian/Einsteinian secular precessions of several solar system planets recently estimated by independent teams of astronomers. We obtain the following approximate lower bounds on d _X for the assumed masses of X quoted in brackets: 150–200 au (Mars), 250–450 au \(({0.7 m_{\oplus}})\), 3500–4500 au (4 m _Jup).  相似文献   

Predictive potential of Perzyna viscoplastic modelling for granular geomaterials     

Maria Lazari  Lorenzo Sanavia  Claudio di Prisco  Federico Pisanò 《国际地质力学数值与分析法杂志》2019,43(2):544-567

This paper reappraises Perzyna-type viscoplasticity for the constitutive modelling of granular geomaterials, with emphasis on the simulation of rate/time effects of different magnitude. An existing elasto-plastic model for sands is first recast into a Perzyna viscoplastic formulation and then calibrated/validated against laboratory test results on Hostun sand from the literature. Notable model features include (1) enhanced definition of the viscous nucleus function and (2) void ratio dependence of stiffness and viscous parameters, to model the pycnotropic behaviour of granular materials with a single set of parameters, uniquely identified against standard creep and triaxial test results. The comparison between experimental data and numerical simulations points out the predicative capability of the developed model and the complexity of defining a unique viscous nucleus function to capture sand behaviour under different loading/initial/boundary and drainage conditions. It is concluded that the unified viscoplastic simulation of both drained and undrained response is particularly challenging within Perzyna's framework and opens to future research in the area. The discussion presented is relevant, for instance, to the simulation of multiphase strain localisation phenomena, such as those associated to slope stability problems in variably saturated soils.  相似文献